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Synthesis of mono- and diphosphorus phosphazane oligomer/polymer precursors

✍ Scribed by Bent, Elizabeth G.; Schaeffer, Riley; Haltiwanger, R. Curtis; Norman, Arlan D.


Book ID
126125730
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
884 KB
Volume
29
Category
Article
ISSN
0020-1669

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Original and efficient synthesis of 2:1-
✍ Cécile Abbas; Guillaume Pickaert; Claude Didierjean; Brigitte Jamart Grégoire; R 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 325 KB

The preparation of 2:1-[a/aza]-oligomer precursors is described via Mitsunobu and exchange of protecting groups protocols in four steps in good yields starting from N-tert-butyloxycarbonylaminophtalimide. Conformational studies showed that these building blocks further led to b-turn-like folded 2:1-