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Synthesis of methyl 4-0-(dichlorodimethoxy-o-orsellinyl)-2,6-dideoxy-a-D-arabino-hexopyranoside (methyl glycoside of methylcuracin)

✍ Scribed by Gros, Eduardo G.; Gruneiro, Elena M.


Book ID
126406274
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
608 KB
Volume
36
Category
Article
ISSN
0022-3263

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Synthesis of Methyl 2,6-Dideoxy-4-thio-α
✍ Claßen, Arnold ;Scharf, Hans-Dieter 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 549 KB

## Abstract The 4‐thio analog of 2,6‐dideoxy‐D‐__ribo__‐hexopyranose (D‐digitoxose) is part of the saccharide chain of the calicheamicins and esperamicins. A straightforward synthesis of the 4‐thiodigitoxoside 12 as its diacetate 13 starting from methyl α‐D‐galactopyranoside (1) is described. Prope