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Synthesis of Metal-containing Polymers via Ring Opening Metathesis Polymerization (ROMP). Part I. Polymers Containing Main Group Metals

✍ Scribed by Valerian Dragutan; Ileana Dragutan; Helmut Fischer

Publisher: Springer
Year: 2007
Tongue: English
Weight: 750 KB
Volume: 18
Category: Article
ISSN: 1053-0495
DOI: 10.1007/s10904-007-9185-5

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The reaction of one equivalent of dilithiated O(SiMe 2 -Ap-H) 2 Cl(THF) Bu 4 N (5), O(SiMe 2 -Ap) 2 Y(BH 4 ) 2 Na(THF) 2 (6) and O(SiMe 2 -Ap) 2 Y(CH(TMS) 2 ) 2 Li(THF) 3 ( ), respectively. The [Ap-H = -N(2-amino-4-methylpyridine)] (1), generated in situ, with LnCl 3 (Ln = Y, Sm) in THF affords O(Si