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Synthesis of [(mes)OsH(CH3)CO] from [(mes)OsCl2]n and C2H5OH. Controlled fragmentation of ethanol into CH3, H, CO, and H2 by a transition-metal center

โœ Scribed by Stahl, Stefan; Werner, Helmut


Book ID
127281621
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
512 KB
Volume
113
Category
Article
ISSN
0002-7863

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Silanediols Derived from Silanetriols. X
โœ Murugavel, Ramaswamy ;Voigt, Andreas ;Chandrasekhar, Vadapalli ;Roesky, Herbert ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Wiley (John Wiley & Sons) ๐ŸŒ English โš– 436 KB ๐Ÿ‘ 2 views

The silanediols RN(SiMe3)Si(OSiMe3)(0H)2 (R = 2,4,6-were characterized by means of mass, IR and NMR (lH and Me3C6H2 4, 2,6-Me2C6H3 5 , and 2,6-iPr2C6H3 6) were prepa-2gSi) spectroscopy. Additionally, the molecular structures of red by the reactions of the respective silanetriols RN(SiMe3)-4 and 7 we