Control of chemo- and regio-selectivity
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David J. Bergmann; Eva M. Campi; W.Roy Jackson; Quentin J. McCubbin; Antonio F.
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Article
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1997
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Elsevier Science
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French
โ 148 KB
The rhodium catalysed reactions of N-allyl-and N-butenyl-l,3-diaminopropanes give single products arising from exclusive hydroformylation at the terminal carbon when the hindered bisphosphite ligand, BIPHEPHOS is used. Reactions using a high carbon monoxide : hydrogen ratio (9 : I) and triphenylphos