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Synthesis of macromers by means of living polymers and their polymerizabilities

โœ Scribed by Asami, Ryuzo ;Takaki, Mikio


Publisher
Wiley (John Wiley & Sons)
Year
1985
Weight
492 KB
Volume
12
Category
Article
ISSN
0025-116X

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๐Ÿ“œ SIMILAR VOLUMES


Synthesis of polymers containing conjuga
โœ Takahide Mizawa; Katsuhiko Takenaka; Tomoo Shiomi ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 154 KB ๐Ÿ‘ 2 views

In order to synthesize end-functionalized polymers with conjugated dienyl groups, living polymeric anions of polystyrene and polyisoprene were allowed to react with 5-bromo-1,3-pentadiene, 1, and 7-bromo-1,3-heptadiene, 2. The reaction of polystyryl anion and/or polyisoprenyl anion with 1 gave polym

Synthesis of end-functionalized polymers
โœ Katsuhiko Takenaka; Akira Hirao; Seiichi Nakahama ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 468 KB

Both polystyrenes and polyisoprenes with 1,3-butadienyl end-groups were synthesized by the reactions of polystyryl and polyisoprenyl anions with 6-bromo-3-methylene-1 -hexene (3). The 1,3-butadienyl end-group was further transformed to an anhydride function by Diels-Alder reaction with maleic anhydr

Synthesis of end-functionalized polymer
โœ Kenji Sugiyama; Akira Hirao; Seiichi Nakahama ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 916 KB

## Abstract Reactions of anionic living polymers of styrene, __tert__โ€butyl methacrylate, and 2โ€(trimethylsiloxy)ethyl methacrylate with perfluoroalkyl (Rf) halides, such as C~4~F~9~(CH~2~)~3~I(1), (CF~3~)~2~CF(CF~2~)~6~I (2), C~4~F~9~(CH~2~)~2~I (3), C~8~F~17~(CH~2~)~2~O(CH~2~)~4~Br (4), were inve