Synthesis of Macrocyclic, Triazine-Based Receptor Molecules
✍ Scribed by Dennis W. P. M. Löwik; Christopher R. Lowe
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 836 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-193X
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📜 SIMILAR VOLUMES
## Abstract The crystal and molecular structure of the complex formed by the ionized bistartro‐[18]‐crown‐6 receptor molecule **1** with the ethylenediammonium cation, is described. The macrocycle is roughly planar, the carboxy groups of each tartaric acid residue being in a diaxial relationship an
Macrocyclic receptor 1 has been synthesised, as a racemate and as a single enantiomer, utilising a Stille coupling for the formation of the biphenyl portion and a macrolactamisation as the final step. The binding properties for the racemic and the homochiral macrocycle with amino acid and dipeptide