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Synthesis of macrocyclic propargylic alcohols by ene-type cyclization of unsaturated acetylenic aldehydes

✍ Scribed by Marshall, James A.; Andersen, Marc W.

No coin nor oath required. For personal study only.

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The enantioselective synthesis of propargylic alcohols was achieved by enantioselective allyltitanation of acetylenic aldehydes.

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