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Synthesis of Large Ring Macrocycles (12-18) by Recyclable Palladium-Complexed Dendrimers on Silica Gel Catalyzed Intramolecular Cyclocarbonylation Reactions.

✍ Scribed by Shui-Ming Lu; Howard Alper

Book ID
102009032
Publisher
John Wiley and Sons
Year
2007
Weight
24 KB
Volume
38
Category
Article
ISSN
0931-7597

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Synthesis of Large Ring Macrocycles (12–
Synthesis of Large Ring Macrocycles (12–18) by Recyclable Palladium-Complexed Dendrimers on Silica Gel Catalyzed Intramolecular Cyclocarbonylation Reactions
✍ Shui-Ming Lu; Howard Alper 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 183 KB

## Abstract Intramolecular cyclocarbonylation reactions with palladium‐complexed dendrimers on silica gel as catalysts are very effective for the synthesis of twelve‐ to eighteen‐membered ring macrocycles. This process can tolerate a wide variety of functional groups, including halide, ether, keton