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Synthesis of isoindolin-1-ones via palladium-catalyzed intermolecular coupling and heteroannulation between 2-iodobenzoyl chloride and imines

✍ Scribed by Chan Sik Cho; Hyung Sup Shim; Heung-Jin Choi; Tae-Jeong Kim; Sang Chul Shim; Myung Chul Kim

Book ID: 104210281
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 100 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)00495-0

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✦ Synopsis

2-Iodobenzoyl chloride reacts with an array of imines in acetonitrile-methanol under carbon monoxide pressure in the presence of a catalytic amount of bis(triphenylphosphine)palladium(II) chloride/triphenylphosphine together with triethylamine to afford the corresponding isoindolin-1-ones in moderate yields.

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