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Synthesis of ionic liquid-supported hypervalent iodine reagent and its application as a ‘catch and release’ reagent for α-substituted acetophenones

✍ Scribed by Muthyala, Manoj Kumar; Choudhary, Sunita; Kumar, Anil

Book ID
121504994
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
927 KB
Volume
4
Category
Article
ISSN
2046-2069

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Optically active, polycarbodiimides 3(a, b & c) with pyridine pendant groups were synthesized using [(R) e 2,2 0 -binaphthoxy] (di-isopropoxy) titanium(IV) catalyst. The polymers were characterized by 1 H and 13 C NMR, and IR. Thermal stability of these polymers (up to 162 C by TGA), allows thermall