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Synthesis of insect trail pheromones: The isomeric 3-butyl-5-methyloctahydroindolizines

โœ Scribed by Philip E. Sonnet; James E. Oliver


Book ID
112123403
Publisher
Journal of Heterocyclic Chemistry
Year
1975
Tongue
English
Weight
458 KB
Volume
12
Category
Article
ISSN
0022-152X

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Synthesis of [ฮฒ-4,5-3H]-cholestan-3-one,
โœ James P. DiBattista; Francis X. Webster ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ French โš– 145 KB ๐Ÿ‘ 1 views

Hydrogenation of 4-cholesten-3-one (1) with tritium gas over palladium black in pyridine afforded [P-4,5-SH]-cholestan-3-one (2a). Tritium NMR showed that there was a mixture of tritiated compounds formed, 2a-2c; the latter two containing small amounts of protium substitution. Tritium NMR also indi