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Synthesis of Indoleacetic Acid from Glutamic Acid and a Proposed Mechanism for the Conversion 1

✍ Scribed by Fox, Sidney W.; Bullock, Milon W.

Book ID
126219643
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
277 KB
Volume
73
Category
Article
ISSN
0002-7863

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An improved procedure for the synthesis
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## Abstract A convenient two‐step chemical synthesis of DL‐[2‐^13^C]‐glutamic acid from methyl acrylate and diethyl acetamidomalonate is described. Synthesis of the Michael adduct (III) was effected in quantitative yield by employing strong amino bases as catalysts. The reactivities of three such c