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Synthesis of Iminosugars from α,β-Unsaturated Lactones and N-Benzyl Nitrone.

✍ Scribed by I. Panfil; Z. Urbanczyk-Lipkowska; M. Chmielewski


Publisher
John Wiley and Sons
Year
2005
Weight
31 KB
Volume
36
Category
Article
ISSN
0931-7597

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The 1,3-dipolar cycloaddition of cyclic nitrones to several "t-bromo ct,~unsaturated esters and lactones has been studied. All the reactions have shown high stereoselectivity, with a predominance of the endo or exo transition state for the trans or cis dipolarophiles, respectively.