Hyperbranched polymers were produced using glycidyl methacrylate (GMA)/Cp 2 TiCl 2 /Zn as selfcondensing vinyl polymerization (SCVP) system. The polymerization is firstly initiated by the epoxide radical ring opening catalyzed by Cp 2 Ti(III)Cl generated in situ via the reaction of Cp 2 TiCl 2 with
✦ LIBER ✦
Synthesis of hyperbranched polymers via a facile self-condensing vinyl polymerization system – Glycidyl methacrylate/Cp2TiCl2/Zn
✍ Scribed by Xiao-hui Liu; You-mei Bao; Xiu-lan Tang; Yue-sheng Li
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 450 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0032-3861
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## Abstract Hyperbranched poly(glycidyl methacrylate) (PGMA) and poly(GMA‐__co__‐styrene) have been synthesized by the self‐condensing vinyl polymerization of GMA and the copolymerization of GMA and St. Cp~2~Ti(III)Cl catalyzed the epoxy groups to produce initiating radicals and Cu(II)X~2~ (X = Br