Synthesis of Hyperbranched Poly(ester)s with Pendant Hydroxy Groups by the Polyaddition of Bis(oxetane)s with 1,3,5-Benzenetricarboxylic Acid
β Scribed by Nishikubo, Tadatomi; Kudo, Hiroto; Nakagami, Takehiko
- Book ID
- 119987507
- Publisher
- Nature Publishing Group
- Year
- 2006
- Tongue
- English
- Weight
- 149 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0032-3896
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π SIMILAR VOLUMES
Addition reaction of (3-methyl-3-oxetanyl)methyl acetate (MOMA) with bis(4-mercaptophenyl) sulfide (BMPS) was examined in certain organic solvents. When the reaction of MOMA with BMPS was performed without any catalyst in hexamethylphosphoric triamide (HMPA) and N-methyl-2-pyrrolidone (NMP) at 130Β°C
The polyaddition of bis(3-ethyl-3-oxetanylmethyl) terephthalate (BEOT) with dichlorodiphenylsilane (CPS) using tetrabutylammonium bromide (TBAB) as a catalyst proceeded under mild reaction conditions to afford a polymer containing silicon atoms in the polymer main chain. A poly(silyl ether) (P-1) wi
The polyaddition of 1,4-bis [(3-ethyl-3-oxetanyl)methoxymethyl]benzene (BEOB) with 3,3Π,5,5Π-tetrachlorobisphenol A (TCBPA) was examined with or without catalysts. High molecular weight polymer (polymers 1) (M n Ο 13,600) with pendant primary hydroxyl groups was obtained in a 99% yield without any g
## Abstract A new polyaddition of bis(oxetare)s with diacyl chlorides catalyzed by quaternary onium salts is described. The reactions of the new bifunctional monomer, bis(3βmethylβ3βoxetanylmethyl) terephthalate, with terephthaloyl chloride using quaternary ammonium halides proceed smoothly under m
New reactive polymers with pendant halomethyl groups were successfully synthesized by polyaddition reactions of bis(epoxide)s with bis(chloroacetoxy)ester such as 1,4-bis[(chloroacetoxy)methyl]benzene (BCAMB) or 1,4-bis[(bromoacetoxy)methyl]benzene (BBAMB) using quaternary onium salts or crown ether