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Synthesis of Hyperbranched Poly(ester)s with Pendant Hydroxy Groups by the Polyaddition of Bis(oxetane)s with 1,3,5-Benzenetricarboxylic Acid

✍ Scribed by Nishikubo, Tadatomi; Kudo, Hiroto; Nakagami, Takehiko


Book ID
119987507
Publisher
Nature Publishing Group
Year
2006
Tongue
English
Weight
149 KB
Volume
38
Category
Article
ISSN
0032-3896

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## Abstract A new polyaddition of bis(oxetare)s with diacyl chlorides catalyzed by quaternary onium salts is described. The reactions of the new bifunctional monomer, bis(3‐methyl‐3‐oxetanylmethyl) terephthalate, with terephthaloyl chloride using quaternary ammonium halides proceed smoothly under m

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New reactive polymers with pendant halomethyl groups were successfully synthesized by polyaddition reactions of bis(epoxide)s with bis(chloroacetoxy)ester such as 1,4-bis[(chloroacetoxy)methyl]benzene (BCAMB) or 1,4-bis[(bromoacetoxy)methyl]benzene (BBAMB) using quaternary onium salts or crown ether