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Synthesis of Hyperbranched Carbohydrate Polymer by Ring-Opening Multibranching Polymerization of 1,4-Anhydroerythritol and 1,4-Anhydro- l -threitol

✍ Scribed by Imai, Tomoko; Satoh, Toshifumi; Kaga, Harumi; Kaneko, Noriaki; Kakuchi, Toyoji


Book ID
118180109
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
129 KB
Volume
37
Category
Article
ISSN
0024-9297

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Synthesis of Hyperbranched Carbohydrate
✍ Toshifumi Satoh; Toyoji Kakuchi πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 232 KB

## Abstract The synthesis of novel hyperbranched carbohydrate polymers, prepared by the ring‐opening multibranching polymerizations of anhydro and dianhydro sugars, is described. The hyperbranched carbohydrate polymers were formed by the cationic polymerization of 1,6‐anhydro‐__Ξ²__‐D‐hexopyranose,

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Three new 1,4-anhydro-glucopyranose derivatives having different hydroxyl protective groups such as 1,4-anhydro-2,3,6-tri-O-methyl-a-D-glucopyranose (AMGLU), 1,4-anhydro-6-O-benzyl-2,3-di-O-methyl-a-D-glucopyranose (A6BMG), and 1,4-anhydro-2,3-di-O-methyl-6-O-trityl-a-D-glucopyranose (A6TMG) were sy