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Synthesis of Hyperbranched and Highly Branched Methacrylates by Self-Condensing Group Transfer Copolymerization

✍ Scribed by Simon, Peter F. W.; Müller, Axel H. E.


Book ID
126131405
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
106 KB
Volume
34
Category
Article
ISSN
0024-9297

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Hyperbranched methacrylates by self-cond
✍ Peter F. W. Simon; Wolfgang Radke; Axel H. E. Müller 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 450 KB

## Abstract The synthesis of hyperbranched methacrylates was achieved by self‐condensing group transfer polymerization of 2‐(2‐methyl‐1‐triethylsiloxy‐1‐propenyloxy)ethyl methacrylate (1). “Back‐biting” is shown to be the predominant side reaction. In spite of this, the compact nature of the hyperb