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Synthesis of hydroxyl-terminated polybutadiene possessing high content of 1,4-unitsviaanionic polymerization

✍ Scribed by Ji-ming Chen; Zai-jun Lu; Guang-qin Pan; Yong-xin Qi; Jian-jun Yi; Hai-jian Bai


Book ID
106280690
Publisher
Institute of Chemistry Chinese Academy of Sciences
Year
2010
Tongue
English
Weight
409 KB
Volume
28
Category
Article
ISSN
0256-7679

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The catalytic system Co/methylaluminoxane/tert-butyl chloride has been studied and optimized for the polymerization of 1,3-butadiene to high cis-1,4-polybutadiene. The ratio of the individual catalyst components was investigated to achieve maximum conversion, stereoregularity, and molecular weight.