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Synthesis of hybrid ligands derived from benzil, thiosemicarbazide and heteroaromatic hydrazides and their reactivity with group 12 metals

✍ Scribed by Calatayud, David G.; López-Torres, Elena; Antonia Mendiola, M.


Book ID
121709685
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
719 KB
Volume
54
Category
Article
ISSN
0277-5387

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## Abstract Diethyl [1′‐(diphenylphosphanyl)ferrocenyl]phosphonate (1) was synthesised by stepwise metallation/functionalisation of 1,1′‐dibromoferrocene and studied as a ligand for palladium(II) and group‐12 metals. Treatment of [PdCl~2~(cod)] (cod = η^2^:η^2^‐cycloocta‐1,5‐diene) with 1 in 1:1 or