Polyether dendrons have been successfully used as macroinitiators for the living ring-opening polymerization (ROP) of lactones and lactides. A hydroxyl group located at the focal point of dendrimers of different generations was transformed into diethyl aluminum alkoxides by reaction with triethyl al
✦ LIBER ✦
Synthesis of hybrid dendritic-linear block copolymers with dendritic initiators prepared by convergent living anionic polymerization
✍ Scribed by Hasan A. Al-Muallem; Daniel M. Knauss
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 156 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0887-624X
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The preparation and chemical modification of dendritic-linear block copolymers with surface functionalized dendritic components are presented. Isophthalate ester-functionalized dendrons featuring benzylic halide groups at their focal points have been used for the metal catalyzed ''living'' radical p