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Synthesis of Homoleptic Ruthenium “Star” Complexes by Click Reaction for TiO 2 Sensitization

✍ Scribed by Chitre, Keyur P.; Guillén, Elena; Yoon, Audri Soojin; Galoppini, Elena


Book ID
118758196
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
454 KB
Volume
2012
Category
Article
ISSN
1434-1948

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Irradiation of acidic (pH 2) solutions of RuLb+ 2C1-(L = diisopropyl 2,2'-bipyridine-4,4'-dicarboxylate) in the presence of TiO, at 100°C leads to the loss of one bipyridyl ligand and the chemical fixation of RuL, at the surface of the TiO, particles through formation of Ru-0-Ti bonds. These surface