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Synthesis of Highly Substituted 1,3-Butadienes by Palladium-Catalyzed Arylation of Internal Alkynes

✍ Scribed by Tetsuya Satoh; Shinji Ogino; Masahiro Miura; Masakatsu Nomura

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 167 KB
Volume: 43
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200460409

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## Abstract Various 1,3‐diaryl‐2‐arylethynyl‐1,3‐butadienes **7** have been prepared by the Pd‐catalyzed trimerization of arylalkynes **4**. Their structures and stereochemistry have been confirmed by X‐ray crystal analyses. This procedure provides high regioselectivity to generate adducts __Z__‐**