Synthesis of high-performance composites by in situ polycondensation and their mechanical properties

✍ Scribed by Kohei Sanui; Yoshiko Kiyohara; Masahiro Rikukawa; Naoya Ogata

• Publisher: Elsevier Science
• Year: 1996
• Tongue: English
• Weight: 540 KB
• Volume: 30
• Category: Article
• ISSN: 1381-5148
• DOI: 10.1016/1381-5148(96)00019-3

✦ Synopsis

High-performance composites of vinylpyridine-styrene copolymers and polyamic acid (PAA) were prepared by the socalled 'in situ polymerization method'. Poly(4-vinylpyridine-co-styrene) (P4VPy-St) and poly(2-vinylpyridine-co-styrene) (P2VPy-St) were used as flexible matrix polymers. A molecular composite could be obtained from a polymer pair having an attractive interaction such as a coulombic interaction. Their morphologies were observed by scanning electron microscopy (SEM); mechanical properties of these composites were studied by tensile tests. The PAA content dependence of tensile strength for the composite films obtained by the in situ polymerization method was investigated. The tensile strength of the resulting composite was about 1.5 times higher than that of PAA film. The coulombic interaction between the pyridine moiety in the matrix copolymer and resulting PAA enhanced both the miscibility and mechanical properties of the composites. Furthermore, a polyimide (PI) structure was formed by stepwise heat-treatment and greatly enhanced the tensile strength of the composite films.