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Synthesis of Heterosubstituted Hexaarylbenzenes via Asymmetric Carbonylative Couplings of Benzyl Halides

✍ Scribed by Potter, Robert G.; Hughes, Thomas S.


Book ID
127322502
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
114 KB
Volume
9
Category
Article
ISSN
1523-7060

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Reaction of in situ generated lithium fluorenide salts with cobalt chloride results in formation of the corresponding bifluorenes. The scope of fluorenes that can be coupled include those containing substituents amenable to polymerization for application to poly(bifluorene) synthesis and alkyl subst