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Synthesis of heterometallic carbide clusters containing three iron atoms: [PPN]2[MFe3(CO)13C] (M = Cr, W), [PPN]2[Cr2Fe3(CO)16C], Rh2Fe3(CO)14C, and [PPN][Rh3Fe3(CO)15C]

โœ Scribed by Hriljac, Joseph A.; Holt, Elizabeth M.; Shriver, Duward F.


Book ID
125943427
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
920 KB
Volume
26
Category
Article
ISSN
0020-1669

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Heterometallic Nitrido-Carbonyl Clusters
โœ Roberto Della Pergola; Massimiliano Branchini; Alessandro Fumagalli; Luigi Garla ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 326 KB ๐Ÿ‘ 2 views

The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit