Synthesis of (Hemi)Carceplex Adsorbates for Self-Assembly on Gold

✍ Scribed by Bart-Hendrik Huisman; Dmitry M. Rudkevich; Angeles Farrán; Willem Verboom; Frank C. J. M. van Veggel; David N. Reinhoudt

• Publisher: John Wiley and Sons
• Year: 2000
• Tongue: English
• Weight: 333 KB
• Volume: 2000
• Category: Article
• ISSN: 1434-193X
• DOI: 10.1002/(sici)1099-0690(200001)2000:2<269::aid-ejoc269>3.0.co;2-f

✦ Synopsis

The synthesis of sulfide-functionalized (hemi)carceplexes prepared by the combination of two different resorcin[4]arenes, 3 and 10. These adsorbates form ordered self-suitable for self-assembly on gold is described. A noncentrosymmetrical carceplex 9 (guest DMF) was synthesized by the assembled monolayers on gold with their quasi C 4v axis perpendicular to the surface. The two positions possible for combination of calix[4]arene 4 and resorcin[4]arene 3, while a noncentrosymmetrical hemicarceplex 12 (guest NMP) was the incarcerated guest lead to diastereotopic surfaces.

tations for a number of guests in the carceplex, and, in ad- [a]