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Synthesis of glutarimide antibiotics and their analogs through 1,3-cycloaddition of 3-glutarimidylacetonitrile oxide to 2-cyclohexenones

✍ Scribed by A. A. Akhrem; F. A. Lakhvich; V. A. Khripach; I. B. Klebanovich

Book ID
112331408
Publisher
Springer US
Year
1979
Tongue
English
Weight
437 KB
Volume
15
Category
Article
ISSN
0009-3122

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✍ Mohammed I.M Wazeer; Herman P Perzanowski; Sajid I Qureshi; Mohammad B Al-Murad; πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 201 KB

The stereochemistry and reactivity of the cycloaddition reactions of a heterocyclic nitrone, 2,3,4,5,-tetrahydropyrazine 1-oxide, have been studied. The heterocyclic nitrone is found to be more reactive than its carbocyclic counterpart. The nitrone underwent regio-and stereo-selective cycloaddition