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Synthesis of Glucose-Containing Polyaniline by the Oxidative Polymerization of N-Glucosylaniline

โœ Scribed by Jun-ichi Kadokawa; Yuusuke Shinmen; Shin-ichiro Shoda


Book ID
102496277
Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
103 KB
Volume
26
Category
Article
ISSN
1022-1336

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โœฆ Synopsis


Abstract

Summary: The oxidative polymerization of Nโ€glucosylaniline was carried out using ammonium persulfate as the oxidant in phosphate buffer. The structure of the isolated polymer was determined by ^1^H NMR, ^13^C NMR, and UVโ€vis spectroscopy to be the polyaniline having glucose residues attached to the general polyaniline unit. Participation of the orthoโ€position of the aromatic ring in the polymerization was also confirmed by the analyses.

The oxidative polymerization of Nโ€glucosylaniline.

imageThe oxidative polymerization of Nโ€glucosylaniline.


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Electrochemical behaviour of polyaniline
โœ R. Maลพeikienรจ; A. Malinauskas ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 522 KB

Polyaniline modified electrodes were prepared following a two step procedure: (i) electrodeposition of manganese dioxide from an alkaline permanganate solution, and (ii) chemical polymerization of aniline on the electrode surface by a manganese dioxide layer. Electrochemical behaviour of the obtaine