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Synthesis of ginsenoside Rh2 and chikusetsusaponin-LT8 via gold(I)-catalyzed glycosylation with a glycosyl ortho-alkynylbenzoate as donor

✍ Scribed by Jinxi Liao; Jiansong Sun; Yiming Niu; Biao Yu

Book ID: 104099149
Publisher: Elsevier Science
Year: 2011
Tongue: French
Weight: 500 KB
Volume: 52
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2011.04.003

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✦ Synopsis

Glycosylation of the acid labile protopanaxadiol derivatives was succeeded with a glycosyl orthohexynylbenzoate as donor under the catalysis of PPh 3 AuNTf 2 , leading to the subsequent elaboration of ginsenoside Rh2 and chikusetsusaponin-LT8 in a concise manner.

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