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Synthesis of functionalized tetrahydro-1,3-diazepin-2-ones and 1-carbamoyl-1H-pyrroles via ring expansion and ring expansion/ring contraction of tetrahydropyrimidines

✍ Scribed by Fesenko, Anastasia A.; Trafimova, Ludmila A.; Shutalev, Anatoly D.


Book ID
111677236
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
608 KB
Volume
10
Category
Article
ISSN
1477-0520

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πŸ“œ SIMILAR VOLUMES


Single and Double Stereoselective Ring E
✍ Dumitriu, Angela ;Elian, Mihai ;ClorΓ’nescu, Ecaterin πŸ“‚ Article πŸ“… 1982 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 522 KB

## Abstract The formolysis of __cis__‐ and __trans__‐ditosylates **7a** and **7b** yielded the mixed esters **13** (at 55Β°C) or the diols **11** (at 100Β°C, after LAH reduction) by single and double ring expansion, respectively. The reactions are stereoselective, occurring with retention of configur