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Synthesis of Functionalized Diarylmethanes via a Copper-Catalyzed Cross-Coupling of Arylmagnesium Reagents with Benzylic Phosphates

โœ Scribed by Kofink, Christiane C.; Knochel, Paul


Book ID
126396577
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
89 KB
Volume
8
Category
Article
ISSN
1523-7060

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Highly selective synthesis of allylated
โœ Ei-ichi Negishi; Hajime Matsushita; Nobuhisa Okukado ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 235 KB

The Pd-catalyzed cross coupling of either benzylzincs with alkenyl halides or alkenylalanes with benzyl halides provides highly selective and expeditious routes to allylated arenes. We have recently reported a highly selective Pd-catalyzed allylation of alkenyl-and arylmetals. 4 In view of the signi