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Synthesis of functionalized cyclotriveratrylene analogues with C1-symmetry and the application for 1,4-Michael addition of alcohols to unsaturated aryl ketone

✍ Scribed by Song, Jing-Ru; Huang, Zhi-Tang; Zheng, Qi-Yu


Book ID
120552795
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
728 KB
Volume
69
Category
Article
ISSN
0040-4020

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A simple method for the direct synthesis of 2,2%-binaphthols was developed, utilizing aryl-aryl coupling reaction via electron donor-acceptor complexes of 1-naphthols with SnCl 4 . Heating of the complex in a sealed tube afforded the corresponding o-o coupling product in excellent yield. This method