✦ LIBER ✦

Synthesis of Functionalized Bicyclo[3.2.1]octan-6-ones for Diterpenoids: Allylsilane Directed Pummerer Reaction: Insertion Reactions of Diazoketones.

✍ Scribed by Philip Magnus; Trevor Rainey; Vince Lynch

Publisher: John Wiley and Sons
Year: 2003
Weight: 152 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200326191

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis of functionalized bicyclo[3.2.

Synthesis of functionalized bicyclo[3.2.1]octan-6-ones for diterpenoids: allylsilane directed Pummerer reaction: insertion reactions of diazoketones

✍ Philip Magnus; Trevor Rainey; Vince Lynch 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 144 KB

The sulfide 5 underwent Pummerer cyclization to give 6, whereas the allyl silane analog 10 produced the bicyclo[3.2.1]octanones 11 and 11a. Extension of this methodology to 15 resulted in 16 without the necessity for allyl silane activation. The intermediate diazoketone 14 on treatment with BF 3 •OE

A Convergent Strategy for the Asymmetric

A Convergent Strategy for the Asymmetric Synthesis of Enantiomerically Pure Bicyclic Compounds by Using a Silicon-Directed Cycloaddition Reaction: The Synthesis of Enantiomerically Pure Bicyclo[3.2.0]hept-2-en-6-one

✍ Jean-Michel Adam; Léon Ghosez; Kendall N. Houk 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB 👁 2 views

ChemInform Abstract: A Convergent Strate

ChemInform Abstract: A Convergent Strategy for the Asymmetric Synthesis of Enantiomerically Pure Bicyclic Compounds by Using a Silicon-Directed Cycloaddition Reaction: The Synthesis of Enantiomerically Pure Bicyclo[3.2.0]hept-2-en-6-one.

✍ Jean-Michel Adam; Leon Ghosez; Kendall N. Houk 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views