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Synthesis of Fluorinated Telechelic Diols Based on 3,3,3-Trifluoropropene as Precursors of Well-Defined Fluoropolymers

✍ Scribed by Kostov, Georgi K.; Lopez, Gérald; Brandstadter, Stephan M.; Edwards, Bradley E.; Améduri, Bruno


Book ID
126789562
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
403 KB
Volume
16
Category
Article
ISSN
1523-7060

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## Abstract The benzo[__a__]heptalene formation from 4‐[(R‐sulfonyl)acetyl]heptalene‐5‐carboxylates **15** and 5‐[(R‐sulfonyl)acetyl]heptalene‐4‐carboxylates **16** (R=Ph or morpholino) in the presence of R′SO~2~CH~2~Li and BuLi has been investigated (__Scheme 6__). Only the sulfonyl moiety linked