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Synthesis of Fluorinated Cyclopropyl Amino Acid Analogues: Toward the Synthesis of Original Fluorinated Peptidomimetics.

✍ Scribed by Milanole, Gaëlle; Couve-Bonnaire, Samuel; Bonfanti, Jean-François; Jubault, Philippe; Pannecoucke, Xavier

Book ID: 118152792
Publisher: American Chemical Society
Year: 2012
Tongue: English
Weight: 684 KB
Volume: 78
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo302222n

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## Abstract This account concentrates on our new methodologies for the synthesis of fluorine analogues of amino acids and their derivatives using the Reformatsky‐type reactions of ethyl bromodifluoroacetate and ethyl dibromofluoroacetate with imines promoted by the Wilkinson catalyst. First, we pre