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Synthesis of fluorescent 4,6,8(14)-trien-3-one steroids via 3,5,7-trien-3-ol ethers. Important probes for steroid-protein interactions

✍ Scribed by Roswitha M. Böhme; Manfred A. Kempfle

Book ID: 116065981
Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 509 KB
Volume: 59
Category: Article
ISSN: 0039-128X
DOI: 10.1016/0039-128x(94)90111-2

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## Abstract The nature of the reactions involved in the synthesis of 3‐cyclopentyloxy‐19‐nor‐17α‐pregna‐3, 5‐dien‐20‐yn‐17‐ol‐7‐^3^H 17‐acetate, allowed the determination of the stereochemistry of the tritium atoms at C‐6 in some of the precursors. One of these precursors was estra‐1, 3, 5 (6)‐trie