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Synthesis of Ferrole Derivatives

✍ Scribed by Doz. Dr. Ernst Bayer; Dr. H. A. Brune; Dipl.-Chem. K. L. Hock


Publisher
John Wiley and Sons
Year
1962
Tongue
English
Weight
121 KB
Volume
1
Category
Article
ISSN
0044-8249

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Addition of dichlorocarbene to the glycal (Β±)-2 followed by cyclopropyl-allyl rearrangement leads to the chloro-2H-pyran (Β±)-4. Oxidation of (Β±)-4 and reduction of the obtained hydroxypyranone (Β±)-5 gave the methyl pyranoside (Β±)-6.