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Synthesis of Extended Linear Aromatics Using Tandem Diels-Alder Aromatization Reactions

✍ Scribed by Morris, J. Larry; Becker, Calvin L.; Fronczek, Frank R.; Daly, William H.; McLaughlin, Mark L.

Book ID
127245448
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
380 KB
Volume
59
Category
Article
ISSN
0022-3263

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Tandem Diels−Alder Aromatization Reactio
Tandem Diels−Alder Aromatization Reactions of Furans under Unconventional Reaction Conditions − Experimental and Theoretical Studies
✍ José M. Fraile; José I. García; María A. Gómez; Antonio de la Hoz; José A. Mayor 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 401 KB

Silica-supported Lewis acids are good catalysts for Diels-Alder reactions between furan and acrylonitrile and methyl acrylate at room temperature. When 2,5-dimethylfuran is used as the diene, yields of the Diels-Alder adducts with methyl acrylate are lower, due in part to the appearance of aromatiza