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Synthesis of exo,exo-5,6-dideuterio-syn-7-acetoxy-norbornene and exo,exo-k,6-dideuterio-2-norbornene

✍ Scribed by Franzus, Boris; Baird, William C.; Surridge, John H.

Book ID
126825741
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
402 KB
Volume
33
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

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✍ Roger Malherbe; Hans Dahn πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 German βš– 699 KB

## Abstract The rate of the acid‐catalysed hydrosis of 7‐__syn__‐diazoacetyl‐2‐norbornene (**1a**) is enhanced relative to that of the saturated analogue **5a** by a factor of 835. In contrast to the behaviour of other primary diazoketones, the substitution step is no longer rate‐determining (mecha