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Synthesis of exo and endo-brevicomin via the rhodium acetate catalyzed cycloaddition reaction of 1-diazo-2,5-hexanedione

✍ Scribed by Albert Padwa; Richard L. Chinn; Lin Zhi

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 241 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99499-1

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✦ Synopsis

Treatment of I-diazo-2,5hexanedione with rhodium (II) acetate in the presence of various aldehydes affords the 6,8-dioxabicyclo[3,2,7]oct~ne ring system in high yield.

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