The authors are indebted to Prof. E. Straube (Halle), Prof. K.-F. Arndt (Dresden) and Prof. J. Kressler (Merseburg) for helpful discussions concerning scattering measurements. Thanks to Chr. Sommer for support in static light scattering experiments.
Synthesis of ethylene oxide/methyl methacrylate diblock copolymers by group transfer polymerization of methyl methacrylate with poly(ethylene oxide) macroinitiators
✍ Scribed by Hendrik Budde; Siegfried Höring
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 491 KB
- Volume
- 199
- Category
- Article
- ISSN
- 1022-1352
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A well-defined linear ABC triblock copolymer of ethylene oxide (EO), methyl methacrylate (MMA), and styrene (St) was prepared by sequential living anionic and photo-induced charge transfer polymerization (CTP) using p-aminophenol as parent compound. In the first step, the diblock copolymer of PEO-b-
The kinetics of photochemical polymerization of styrene (St) and methyl methacrylate (MMA) using a binary initiation system composed of poly(ethylene oxide) with an aniline end group (PEO a ) and benzophenone (BP) was investigated by a modified dilatometer. The effect of the concentration of the mon