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Synthesis of enethiolisable α-oxothiones by flash vacuum thermolysis

✍ Scribed by François Bourdon; Jean-Louis Ripoll; Yannick Vallée

Book ID
104228313
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
164 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

The retro Diels-Alder reaction of dihydrooxathiins and the retro-ene reaction of a-allylthio-carbonyl

compounds were used to synthesbe enethiolisable a-oxothiones.

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Flash Vacuum Thermolysis – Synthesis and Characterization of Unstabilized Cycloalkenethiones
✍ Emmanuelle Briard; Jocelyne Levillain; Jean-Louis Ripoll; Yves Dat; Albert Marcu 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 282 KB 👁 1 views

The flash vacuum thermolysis (FVT) of cycloalkenyl allyl (or from cyclopentenethione 1. The obtention of the nonconjugated cycloalkenethiones 2 and 4, expected in the propargyl) sulfides 8, 9, 12, and 13 led, as the main thermal pathway, to the conjugated cycloalkenethiones 1, 3, and 5, FVT of sulfi