Synthesis of Enediynes by Diels–Alder Addition
✍ Scribed by Prof. Henning Hopf; Dipl.-Chem. Marcus Theurig
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 280 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract Four new alicyclic poly{arylene‐9,10‐di[4‐(methyloxy)phenyloxy]‐1,2,3,4,5,6,7,8‐octahydroanthracene‐2,3,6,7‐tetracarboxdiimide}s (APIs) were prepared at 80°C in the presence of NaI in DMSO by the __in situ__ Diels‐Alder polymerization of 1,4‐bis[4‐(methyloxy)phenyloxy]‐2,3,6,7‐tetrakis(
racemization (k) are determined to be ca. 71 kJ/mol and ca. 3.8 x lop3 s -' (39"C), respectively. The energy of racemization found for 1,l for '-binaphthyl (R)and (S)-lb derivatives['']. is comparable The steric to those hindrance caused by two substituents should be smaller in lb than in l a , sinc