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Synthesis of Enantiopure Tetrahydrofurans from Sulfinyl Dienes: Application to the Synthesis of (+)-trans-Kumausyne and (+)-Kumausallene

โœ Scribed by Roberto Fernandez De La Pradilla; Alma Viso


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
33
Category
Article
ISSN
0931-7597

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โœ P. GOSSELIN; E. BONFAND; C. MAIGNAN ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

Application of the Stereoselective Diels-Alder Reaction of Enantiopure 2-Sulfinyl Dienes: Synthesis of (-)-(1S,5R)-Karahana Ether. -The natural karahana ether (VII) is synthesized for the first time by application of sulfinyl derivative (I) as chiral auxiliary in asymmetric Diels-Alder reaction and