Synthesis of Enantiomerically Pure Vinylcyclopropanes by S N 2' Allylic Carboxylate Displacements. -The readily available optically pure lactones (I) or (XIII) undergo palladium-catalyzed displacement by a variety of stabilized carbon, oxygen, and nitrogen nucleophiles to afford as major S N 2' prod
Synthesis of enantiomerically pure vinylcyclopropanes by SN2′ allylic carboxylate displacements
✍ Scribed by Stephen F. Martin; Roy K. Hom; Michael P. Dwyer
- Book ID
- 104262172
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 228 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Enantiomerically pure vinylcyciopropanes were synthesized from selective palladium-catalyzed and coppermediated SN2' nucleophilic reactions of chiral cyclopropyi lactones.
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