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Synthesis of electronically and coordinatively unsaturated complexes [Ru2(CO)4(μ-H)(μ-PtBu2)(μ-L2)] (L2 = biphosphanes)

✍ Scribed by Tobias Mayer; Edris Parsa; Hans-Christian Böttcher


Book ID
116680148
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
563 KB
Volume
696
Category
Article
ISSN
0022-328X

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Electronic structure of two heterotrinuc
✍ M. Velayutham; C.S. Gopinath; S. Subramanian 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 397 KB

Two 1~3-oxo carboxylate-bridged heterotrinuclear (ruthenium, cobalt) [Ru2Co(~3-O)(I.I,-CH3CO2)6L 3] (L = H20, Py) complexes have been prepared. EPR studies at 77 K show that there is no interaction between the ruthenium and cobalt ions. The ground state of high-spin cobalt is a spin doublet and the