✦ LIBER ✦

Synthesis of (E)-diethyl 6,6′-(diazene-1,2-diyl)bis(5-cyano-2-methyl-4-phenylnicotinates), a new type of 2,2′-azopyridine dyes

✍ Scribed by Daniel Botelho da Silva; Abdelouahid Samadi; Lourdes Infantes; María do Carmo Carreiras; José Marco-Contelles

Publisher: Elsevier Science
Year: 2010
Tongue: French
Weight: 622 KB
Volume: 51
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.09.095

No coin nor oath required. For personal study only.

✦ Synopsis

An unexpected, but simple method for the efficient synthesis of new 2.2 0 -azopyridine dyes, such as (E)diethyl 6,6 0 -(diazene-1,2-diyl)bis(5-cyano-2-methyl-4-phenylnicotinates) (2, 4, 6, 8, 10, and 12), based on the treatment of ethyl 6-amino-5-cyano-2-methyl-4-arylnicotinates (1, 3, 5, 7, 9, and 11) with NBS/ benzoyl peroxide, is described. The X-ray diffraction analysis and the UV-vis absorption spectra of dye 2 are reported and discussed.

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis of (E)-Di

ChemInform Abstract: Synthesis of (E)-Diethyl 6,6′-(Diazene-1,2-diyl)bis(5-cyano-2-methyl-4-phenylnicotinates), a New Type of 2,2′-Azopyridine Dyes.

✍ Daniel Botelho da Silva; Abdelouahid Samadi; Lourdes Infantes; Maria do Carmo Ca 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 27 KB 👁 1 views

Synthesis and Structure of 5,5′-[(E,E)-2

Synthesis and Structure of 5,5′-[(E,E)-2,5-Diiodohexa-1,5-diene-1,6-diyl] bis(2,3-dichloro-4,4-dimethoxycyclopent-2-en-1-one).

✍ N. A. Ivanova; Z. R. Valiullina; O. V. Shitikova; E. G. Galkin; D. V. Lyubetskii 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 18 KB 👁 1 views

New Approach to the Synthesis of Substit

New Approach to the Synthesis of Substituted 5-Arylcarbamoyl-3-cyano-6-methylpyridine-2(1H)-thiones (IV). Molecular and Crystal Structure of 2-Allylthio-3-cyano-5-(2-methoxyphenylcarbamoyl)-6-methyl-4- (5-methyl-2-furyl)-1,4-dihydropyridine (VIIb).

✍ V. D. Dyachenko; A. N. Chernega 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 22 KB 👁 2 views

A tetranuclear copper compound containin

A tetranuclear copper compound containing three different types of anions: trans-(μ-tert-butoxy)bis(μ-2,4,6,2′′,4′′,6′′-hexamethyl-1,1′:3′,1′′-terphenyl-2′,2′-diyl)(μ-iodo)tetracopper(I)

✍ Niemeyer, Mark 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 407 KB

Synthesis of (±)-trans-6-[4,4-bis(4-fluo

Synthesis of (±)-trans-6-[4,4-bis(4-fluorophenyl)-3- (1-methyl-1H-tetrazol-5-YL)-1(E),3-[2-14C] butadienyl]-4-hydroxy-3,4,5,6-tetrahydro-2H-pyran-2-one

✍ G. M. Luke; J. E. Swigor 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 French ⚖ 273 KB 👁 1 views

A Facile One-Pot Synthesis of Tetrahydro

A Facile One-Pot Synthesis of Tetrahydropyrimidines. Part 3. Synthesis of [Alkanediylbis(3-alkyl/aralkyl/aryl-3,6-dihydropyrimidine-1,5 (2H)-diyl)]bis(arylmethanones) and [1,4-Phenylenebis(3-phenyl-3,6-dihydropyrimidine-1,5(2H)-diyl)] bis(phenylmethanone).

✍ Milan Ch. Dutta; Kaushik Chanda; Jai N. Vishwakarma 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 17 KB 👁 1 views