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Synthesis of Doubly Unsaturated Aldehydes and Ketones by a Novel β-Decarbopalladation

✍ Scribed by Dr. Hiroto Harayama; Toshitsugu Kuroki; Dr. Masanari Kimura; Dr. Shuji Tanaka; Prof. Dr. Yoshinao Tamaru

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
381 KB
Volume
36
Category
Article
ISSN
0044-8249

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✦ Synopsis

MoKu radiation, Patterson technique, refined against F2, numerical absorption correction, ~(Mo,,) = 10.1 cm-', H atoms freely refined; the calculations were performed with the programs SHELXTL-Plus, SHELXTL, PLATON-94. Depository number CSD-406923. Space group P i , u = 1015 5(1), b =1166.6(1), c =1271.5(1) pm, a =72.79(1), /? =78.79(1), 7 =73.98(1)", V=1372.5(3) A', 2 = 2, psnlcd =1.159 gcm-', 193 K, 10812 measured reflections, 4956 unique reflections with [R,,, = 0.0311, 3283 reflections with F,>40(F,), 419 parameters, R , = 0.027, wR2 (all data) = 0.0557.

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