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Synthesis of doubly bridged p-tert-butyl-calix[6]arene containing hard and soft ion binding sites

โœ Scribed by Yikun Chen; Yuanyin Chen


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
68 KB
Volume
41
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


A conformationally preorganized, C s -symmetrical p-tert-butyl-calix[6]-1,4-crown-4-2,6-dioxo-diazacrown-4 with hard and soft ion binding sites at the lower rim is synthesized. The binding sites may complex alkali metal ions or transition metal ions selectively.


๐Ÿ“œ SIMILAR VOLUMES


Synthesis of two calix[4]arenes in 1,3-a
โœ Wanlapa Aeungmaitrepirom; Zouhair Asfari; Jacques Vicens ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 257 KB

It is reported the synthesis of ligands 6 and $ combining one calix[4]arene unit in the 1,3-alternate conformation and crown ether and aza crown ether elements. Preliminary comp|exations are given.